nanotechnology Electronic and photonic behaviour

Quantum mechanical properties for confinement of electrons in one dimension have long been exploited in solid-state electronics. Semiconductor devices are grown with thin layers of differing composition so that electrons (or “holes” in the case of missing electron charges) can be confined in specific regions of the structure (known as quantum wells). Thin layers with larger energy bandgaps can serve as barriers that restrict the flow of charges to certain conditions under which they can “tunnel” through these barriers—the basis of resonant tunneling diodes. Superlattices are periodic structures of repeating wells that set up a new set of selection rules which affect the conditions for charges to flow through the structure. Superlattices have been exploited in cascade lasers to achieve far infrared wavelengths. Modern telecommunications is based on semiconductor lasers that exploit the unique properties of quantum wells to achieve specific wavelengths and high efficiency.

The propagation of photons is altered dramatically when the size and periodicity of the transient structure approach the wavelength of visible light (400 to 800 nanometres). When photons propagate through a periodically varying dielectric constant—for example, semiconductor posts surrounded by air—quantum mechanical rules define and limit the propagation of the photons depending on their energy (wavelength). This new behaviour is analogous to the quantum mechanical rules that define the motion of electrons through crystals, giving bandgaps for semiconductors. In one dimension, compound semiconductor superlattices can be grown epitaxially with the alternating layers having different dielectric constants, thus providing highly reflective mirrors for specific wavelengths as determined by the repeat distance of layers in the superlattice. These structures are used to provide “built-in” mirrors for vertical-cavity surface-emitting lasers, which are used in communications applications. In two and three dimensions, periodic structures known as photonic crystals offer additional control over photon propagation.

Photonic crystals are being explored in a variety of materials and periodicities, such as two-dimensional hexagonal arrays of posts fabricated in compound semiconductors or stacked loglike arrays of silicon bars in three dimensions. The dimensions of these structures depend on the wavelength of light being propagated and are typically in the range of a few hundred nanometres for wavelengths in the visible and near infrared. Photonic crystal properties based on nanostructured materials offer the possibility of confining, steering, and separating light by wavelength on unprecedented small scales and of creating new devices such as lasers that require very low currents to initiate lasing (called near-thresholdless lasers). These structures are being extensively investigated as the tools for nanostructuring materials are steadily advancing. Researchers are particularly interested in the infrared wavelengths, where dimensional control is not as stringent as at the shorter visible wavelengths and where optical communications and chemical sensing provide motivation for potential new applications.